Fire risks of IBC's

Intermediate Bulk Containers (IBC's)  are used to store and transport many chemicals. A technical advisory bulletin by Willis North America mentions the significantly greater fire hazard the IBC's pose than the classic 55-gallon drum or smaller containers.
They recommend the following:

1. "Protection alternatives should always be investigated (i.e., possible use of off-site IBC storage facilities, etc.).
   The indoor storage of flammable or combustible liquids in nonmetallic or composite IBCs in plant production or warehouse storage areas should be prohibited. 
2. Attempt to store IBCs at a supplier location and receive the materials on a just-in-time basis. 
3. Consider alternatives such as designing and installing a properly protected bulk storage and piping system.
   Consider the use of steel 55-gallon drums or steel IBCs.
   Determine if nonmetallic or composite IBCs are the only method for receiving and storing flammable and combustible liquids in your plant".

Read the advisory in this link. 

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H2S kills again

 The Times of India has reported that two people lost their lives after inhaling H2S gas at a sewage treatment plant. One of the persons who died was a rescuer. Apparently a job of cleaning a pump was in progress when the incident occurred. Six other people were hospitalized.Neither of the two men given the job of cleaning pumps had any safety equipment or gas mask.
Read the article in this link
See a video of H2S safety in this link.

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Fukushima and Process Safety

The Fukushima Nuclear Accident Independent commission has submitted its report. There are lessons to learn from the incident.One of the conclusions of the commission is " Replacing people or changing the names of institutions will not solve the problems.Unless the root causes are resolved, preventive measures against future similar accidents will never be complete. The Commission believes the root causes of this accident cannot be resolved and that the people’s confidence cannot be recovered as long as this “manmade disaster” is seen as the result of error by a specific individual. The underlying issue is the social structure that results in “regulatory capture,” and the organizational, institutional, and legal framework that allows individuals to justify their own actions, hide them when inconvenient, and leave no records in order to avoid responsibility. Across the board, the Commission found ignorance and arrogance unforgivable for anyone or any organization that deals with nuclear power. We found a disregard for global trends and a disregard for public safety. We found a habit of adherence to conditions based on conventional procedures and prior practices, with a priority on avoiding risk to the organization. We found an organization-driven mindset that prioritized benefits to the organization at the expense of the public".


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Runaway reaction incident

The EPA has shared details of a runaway chemical reaction involving phenol formaldehyde reaction. In the incident investigation report,the following recommendations are made:
1. Conduct a thorough hazard assessment
2. Complete identification of reaction chemistry and thermochemistry
3. Ensure human factors are considered in administrative controls
4. Facilities should evaluate capacity of cooling system with respect to controlling unexpected exotherms.
5. Facilities must pay attention to the order of ingredients, the addition rates, under- or over-charging, and loss of agitation.
6. Learn from accident history and near misses

Read the case study in this link.

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Update on reactor blast incident

Further to the reactor blast incident at a pesticide manufacturing facility in Andhra Pradesh, a Times of India newspaper report indicates the following:
"According to experts, there were no control valve and safety rupture disc in the reactor, which exploded following increased temperature. Sources said that employees were testing 'myclo vutanyl', which is used as a pesticide in the agricultural sector, when the blast occurred. Dimethyl sulfoxide (DMSO) and trizol mixture of 8,000 litres in the reactor was tested by night shift employees and the sample sent to the lab. The lab reportedly was not satisfied with the results and the morning batch employees were testing the compound again. During the process, temperature in the reactor shot up to more than 150 degrees centigrade. The block in-charge noticed it and tried to address the problem but it exploded before he could take any action. The fifth block has about 30 reactors and tanks, sources said. A majority of the workers were on tea break during the incident. "Had all the workers been present at the time of the blast, it could have led to fatalities. Eighteen workers got injured as splinters from glasspanes struck them," a worker said'.
 While the root causes of the above incident are under investigation, when operating batch processes, many incidents occur due to lack provision or sizing of  adequate pressure relief devices. This occurs many times due to scaling up of pilot plant trials to plant production without adequately assessing all the reaction data and associated hazards. Have a proper management of change process to address these gaps in a robust way. Read the article in this link.


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A new refinery shutdown by caustic corrosion

 Reuters report that a new refinery in the USA which was being commissioned had an inadvertent slippage of caustic into the system. Apparently the caustic caused severe corrosion of the major equipment in the refinery when the temperature of the unit was increased as part of the start up process. operators came to know of the problem when they started having leaks and fires. The damage apparently is huge and about 50 heat exchangers have to be cleaned. The process hazard analysis of the plant should have spotted the possibility of caustic leaking into the system. While I do not know the reason for the incident, today what I see in HAZOP studies is the competency of the team is coming down and the net result is a poor study output. The onus is more and more on the chair to guide the team properly, No PHA software can do this for you.
Read the Reuters article in this link.

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Massive fire in pesticide plant

A reactor in a pesticide plant apparently exploded about a few hours ago. Many people are feared injured. Read the breaking news in this link.
See photos of the fire in these links:
Link 1
Link 2  
See video in this link.

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More pictures of steel plant accident

The steel plant accident has several probes working to find the root causes. An article in the Hindu mentions three probes - one by the factory Inspector, another by National Legal Service Authority (NALSA)and another by a high level committee to go into the accident and recommend measures to prevent recurrence of such accidents.

The committee, to be headed by former SAIL Chairman S.R. Jain, will investigate the incident and submit a report within a month. I hope we get to see the root causes from all these investigations.

Meanwhile see some more pictures of the accident in this link.

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Micro reactors and inherent safety - the future?

A press release mentions the following:
"Researchers at the Fraunhofer Institute for Chemical Technology ICT in Pfinztal have developed a method for safer production of nitroglycerine: a microreactor process, tailored to this specific reaction. What makes the process safer are the tiny quantities involved. If the quantities are smaller, less heat is generated. And because the surface is very expansive compared to the volume involved, the system is very easy to cool. Another benefit: the tiny reactor produces the explosive material considerably faster than in agitating vessels. Unlike a large agitating vessel filled before the slow reaction proceeds, the microreactor works continuously: the base materials flow through tiny channels into the reaction chamber in “assembly-line fashion“. There, they react with one another for several seconds before flowing through other channels into a second microreactor for processing – meaning purification. This is because the interim product still contains impurities that need to be removed for safety reasons. Purification in the microreactor functions perfectly: the product produced meets pharmaceutical specifications and in a modified form can even be used in nitro capsules for patients with heart disease. “This marks the first use of microreactors in a process not only for synthesis of a material but also for its subsequent processing,“ observes Dr. Stefan Löbbecke, deputy division director at ICT. The microreactor process is already successfully in use in industry".

The use of micro reactors on a large scale will usher in a sea change in process safety. We will be investigating micro explosions instead of the major ones now!!
Read the press release in this link.

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Vehicle movement near flare headers

In March this year, a backhoe knocked a flare header off a pipe rack in a refinery in the USA, leading to a partial evacuation of the refinery. Flare systems including the flare header play a critical part during emergencies, start up and shutdowns. Ensure that you have proper engineering controls (vehicle impact protection) and administrative controls to prevent this happening to your emergency flare/ vent header systems including pipe racks. Read my earlier post on vehicle impact protection in this link.

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Accident at steel plant

Thanks to Deivanayagam for sharing pictures of the steel plant accident. The pictures show the extent of the explosion. The control room damage is also seen. The cause of the incident is being investigated. I hope the incident report is shared so that everyone can learn the lessons.A blast wave can damage everything in its path. Are your control rooms blast proof? See the pictures in this link. (Large file.... be patient)
 
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Pigging accidents

An oil pipelines was being cleaned by "pigging", which involves pushing a cylindrical plug through a pipeline for cleaning it. In this incident the pig was pushed by compressed natural gas. The pig got stuck in the pipeline and natural gas blow through occurred past the pig. The natural gas found its way to pumps and storage tanks and was vented through the tanks safety valves. Luckily it did not catch fire. The investigation determined that the blow through of gas due to a stuck pig was not considered in the job safety analysis. There are many other incidents when a pig receiver cover was opened without proper depressurizing and the pig blasting out, killing the operator. Pigs have known to be blown 100 meters away. Do a proper JSA while pigging.
Read a safety advisory bu the National Energy Board in this link.

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