Inside a chemical plant, a sulphur dichloride (SCl2) leak on a pipeline supplying the boiler tube of a distillation column hydrolysed, thereby generating a strong emission of hydrogen chloride (HCl). 50 ppm of HCl were recorded inside the building. Operating losses were valued at Euros 270,000 (the downstream unit stayed idle for 18 days). A pressure sensor was undergoing maintenance; it had been diagnosed as defective after indicating a reading of 108 mbar of pressure at the boiler tube output, thus triggering closure of the valves controlling SCl2 supply and regulating the vapour heating the boiler tube. Since the sensor was not «fail safe», its electrical disconnection caused the vapour regulation valve to open, thus heating the boiler tube, whose temperature rose from 24° to 120°C in 30 min, and causing the emission of SCl2. Several measures were adopted as part of the feedback provided: monitoring and intervention procedures in a degraded operating mode, modification of the sectional valve / pressure sensor assembly, introduction of a positive safety loop independent of the regulation, thereby prohibiting any automatic restart once the high pressure threshold had been reached. This accident demonstrates that a process control system can in no way be equated with a safety system. More specifically, industrial automation satisfy a rationale and criteria that are not all known by response teams and that do not necessarily incorporate degraded modes and lockouts situations.
Source: Aria ACCIDENT ANALYSIS OF INDUSTRIAL AUTOMATION