On July 14,
maintenance works were completed in a soy beans extraction plant.
Following the inspection by the plant operator, the start-up of the
facility was initiated at 21:30. Steam was admitted to the toaster and
to the jackets of hexane inlet pipes to heat-up the toasters and the
extractor to the proper operating temperatures.
At about 21:45 the
toasters reached their operating temperature and admittance of flakes
commenced through the inlet screw conveyor. After that the night shift
took over. They had some difficulties controlling the process
temperature (dropped), and therefore increased heat supply to the
toaster. About the same time, the sound of the safety flap valve lifting
was heard, and it released hexane and steam into the extractor
building, where the smell of hexane was detected by the operators. The
hexane concentration in the extraction building finally reached a level
which forced the staff out of the extractor building. A bus driver
passing the plant detected the vapours and informed the Traffic Control
Centre that “airplane fuel was spilled on the road”. With this
information, at their arrival, firefighters took a precautionary
approach and parked the fire engine at a safe distance, walking the last
hundreds of meters. The plant manager arrived at the scene and
discussed with the incident commander how to stop the outflow of hexane
vapour, and deciding ultimately to cutoff the power supply to the
extraction plant. The manager there after asked the power control unit
to turn off two transformers under the load. (There was also one
unloaded). Due to inherent risk of possible sparks he rejected stopping
the electrically loaded transformers and instead, disconnected the
third, unloaded transformer. Approximately 30 seconds later, a sudden
fire was observed outside the plant which was followed by a violent
explosion. The explosion injured 27 persons, among 7 emergency
responders and 20 staff members of the plant. The extraction plant was
destroyed by the explosion and was notre-established. The explosion was
probably initiated by the attempt to disconnect one of the three supply
lines to the extraction plant.
Important findings
• Apparently, the smell of hexane which was detected by the operators was not an abnormal occurrence during the start-up.
•
The site also stored large amounts of chlorine and hydrogen in the
facility. Therefore, it was urgent that the incident commander and the
plant manager work quickly together to prevent the explosion.
• The investigation revealed that no emergency shut-down procedure existed for the extraction plant.
Lessons learned
•
Due to the conflict of following orders, the question arises who is in
charge to give orders relating to operation of the plant, is it the
incident commander or the operator? Who makes final decisions to shut
down the electricity? Roles should be identified during normal operation
when the operator drafts the internal emergency plan. The fire brigade
should have visits to the plant to become familiar with the operation
and discuss the emergency procedures with the plant manager and the
control room operators.
• Emergency shut-down operations are crucial
when operating a plant with the hazards of release of toxic materials or
fire/explosion and that these protocols are followed.
• No alarm was
activated to inform the public about the hexane release. Information to
the public and activating the alarm is one of the most important
emergency protocol in case the consequences might affect the nearby
population.
Source: European commission
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