August 22, 2012

Accidents in batch processes

The Safety, Health and Environment Association, Bharuch has posted several incidents on its website. One such incident mentions the following:
"Incident:
During nitration in reactor runaway reaction occurred and suddenly the pressure of reactor raised and explosion took place within few seconds in reactor. Manhole of reactor was opened due to high pressure. Nitric Acid, sulfuric Acid & Benzoic Acid were involved in reaction. In this incident the mixtures of acids were sprayed in process plant, company ground and nearby company. The roof sheets of plant were broken due to explosion. It was sprayed up to about 200 – 300 meters in down wind direction
Cause of Accident:
As per information received from company officials the explosion occurred due to runaway reaction during nitration from reactor of process plant.
Corrective Action
Lime was sprayed on the acidic mixture in whole the affected area in company & on the road also for neutralization. After that the road was washed out with water. Company people also sprayed lime on the acid mixture in their company ground & Process Plant.
Preventive Action
1. Process parameters to be followed strictly.
2. PRV & safety valve to be maintained in working condition with proper venting system.
3. Periodical maintenance & inspection should be done.
4. Employees should be trained in process safety.
5. Laboratory Study for knowledge relative to normal & abnormal known deviation in raw material, Process parameter"

Read more incidents on their website in this link.

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