October 29, 2018

On April 6, 1994, a unit operator was conducting rounds of the coker unit when he observed a leak coming from the mechanical seal of the heavy gas oil pump of coker unit #1. The operator decided to seek assistance; the head unit operator and six or seven unit operators responded. The operators placed water and steam on the leak to suppress the vapor from the seal. The head unit operator decided to shut down the pump and transfer the product to the secondary pump. As the operator shut down the primary pump, the mechanical seal blew, causing a vapor cloud to generate from the seal. The operators continued to put steam and water on the seal and isolated the pump from the pipe line. The remaining product in the pipe line leading to the primary heavy gas oil pump vaporized, leading to the dispersion of the vapor cloud. The operators who responded were wearing bunker gear and several wore emergency respirators. Those with respirators isolated the pump from the pipe line by closing the suction and discharge valves. The operators who were not wearing emergency respirators stationed themselves upwind of the vapor cloud and put water on the cloud; however, the wind changed direction several times, exposing unprotected operators to vapors. Employees #1 and #2, two unprotected operators who responded to incident, were brought to Hospital to be treated for inhalation of hydrocarbons. Employee #1 was hospitalized.
Source: OSHA

October 24, 2018

Hexane Vapors Ignited By Static Electricity; Worker Burned

Employee #1 was standing at the exit end of a conveyor, peeling off a build up of hexane adhesive from the inside of a stainless steel dip tank. A static discharge of electricity, apparently generated by the peeling action, caused a flash fire. Employee #1 suffered second degree burns on the back of his hands and his upper chest and neck. The tank is 12 inches by 15 inches by 22 inches in size. The employee was pulling adhesive from the back side of the tank when the fire started. All the equipment in the area is grounded and bonded and approved for the location. The flash point for hexane is -23 degrees.
Source:OSHA

September 18, 2018

Leak due to vibration

A specialized rubber manufacturing plant experienced leakage of a hexane solution from a pump discharge flange during use. The hexane vapor was ignited by a st atic electricity spark and a fire occurred. Apparently, the flange was loosened by vibrations from the pump.Routine operations were being carried out on site at the time of the accident.
The operation involved the transfer of a hexane solution from an un-reacted raw material recovery tank to the washing process through the outlet of the first flange of the pump. The hexane solution
leaked, ignited, and burned. The financial costs of recovery and lost production were significant.
Causes
The cause of the accident was a loose flange that resulted in leakage of a flammable substance. During the operation, a previously undetected cavitation in the pump produced significant vibration
which loosened the flange. As a cause of the ignition it was considered that the hexane was charged when it spouted from the flange, and static electricity was discharged; then hexane vapor ignited
and a fire occurred.
It was considered that the vibration might have been intensified by the passage of an insoluble polymer lump through the pump, a malformation in the substance generated on the piping wall. In addition, a reducer connected a 3-inch (~75mm) flange of the discharge pump to 6-inch (~150mm) piping. The looseness of this flange might have been accelerated when the force
of vibration was added on the piping.
Lessons learned
Vibrating equipment can increase potential for stress fractures and gaps from loosely fitting interfaces, all of which can be sources of leaks that, if undetected, may result in an accident. It is necessary to pay sufficient attention to vibrating equipment, especially pumps that may be found in many processes throughout the site. Control measures to mitigate potential risks could include regularly scheduled inspections in line with existing technical standards or in-house experience, particular attention to small-bore piping (vulnerable to fatigue), installation of a  vibration monitor to detect and locate abnormal vibration patterns, as well as other measures available in guidance
on vibrations from numerous sources.
Source: European Commission