On January 21, 2023, at 4:30 p.m., 30 pounds of hydrogen gas were accidentally released from a shell-and-tube heat exchanger at a refineryin Louisiana. The released hydrogen caught fire, leading to an emergency shutdown, and caused over $1.5 million in property damage.
The hydrogen release originated from the flange between the heat exchanger channel and shell and occurred during unit startup. The heat exchanger was assembled in 2013 and had undergone 43 thermal cycles. During that time, the bolts had relaxed (a normal event) but had relaxed to the point that the flange could no longer contain the hydrogen within the heat exchanger. The company's investigation found that the bolt torque value used to assemble the heat exchanger in 2013 was too low and should have been much higher to prevent leakage.
CITGO found that the assembly instructions for both the incident heat exchanger and a nearby similar heat exchanger listed incorrect torque values that were too low, as the instructions listed the wrong bolt sizes. In addition, CITGO suspected that since it is common practice at the site to assemble similar flanges to similar torque values, the incorrect torque instructions from the nearby heat exchanger may have been applied to the incident heat exchanger. The company determined that the hydrogen may have ignited from contacting an adjacent hot heat exchanger, friction from the release, or a spark.
Probable Cause
Based on the company's investigation, the CSB determined that the probable cause of the incident was under-torqued bolts that had relaxed during 43 thermal cycles until the flange could not contain the hydrogen within the heat exchanger. Inaccurate assembly instructions and the likely application of incorrect assembly instructions for another heat exchanger contributed to the incident.
Source: CSB.gov